Is there a limit to how much excess baggage I can purchase?

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Yes. Each passenger is allowed a maximum of five pieces or 100 kg (paid excess baggage ) at a time.

To purchase excess baggage login to Manage Booking (you will require PNR/ticket number/FFP number and passenger's last name).
https://booking.qatarairways.com/nsp/views/retrievePnr.xhtml 

Once you retrieve your booking, then click on "Purchase Excess baggage" on the right panel to purchase excess baggage online.

 

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